Very Short Question and Answers - Extraction of Metals
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An ore is a naturally occurring rock containing enough metal or metal compound to make extraction of the metal economically worthwhile.
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The three main steps are: (1) Concentration of ores, (2) Extraction of crude metal, and (3) Refining of the crude metal.
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Highly reactive metals are very reactive and combine with other elements like oxygen and chlorine, so they are never found in free form in nature.
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Electrolysis is used to extract highly reactive metals. For example, sodium is extracted from molten sodium chloride using electrolysis.
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Sodium metal (Na) is deposited at the cathode and chlorine gas (Cl₂) is released at the anode.
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Cryolite is added to alumina (Al₂O₃) to lower its melting point during electrolysis, making the process more energy-efficient.
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Roasting involves heating an ore in the presence of air (for sulphide ores), while calcination involves heating in absence of air (for carbonate ores).
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2ZnS + 3O₂ → 2ZnO + 2SO₂
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Carbon (as coke or charcoal) is commonly used to reduce metal oxides such as Fe₂O₃ and ZnO.
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Fe₂O₃ + 3C → 2Fe + 3CO
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Mercuric oxide is heated strongly, causing it to decompose into mercury and oxygen: 2HgO → 2Hg + O₂.
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Gold (Au) and platinum (Pt) are commonly found in the native (free) state.
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Because these metals are either found native or can be easily obtained by simple heating; electrolysis is not required.
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Gangue is the unwanted materials (like sand, clay, etc.) present in the ore. It is removed during the concentration of ore by methods such as froth flotation or gravity separation.
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Iron is often extracted from its oxide using carbon monoxide as a reducing agent in the blast furnace.
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Aluminium (Al) is extracted by electrolytic reduction of molten alumina (Al₂O₃).
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Refining of metals involves removing impurities from the extracted crude metal to obtain pure metal, often by methods like electrolytic refining.
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Aluminium has a very high affinity for oxygen and forms very stable oxides; carbon is not reactive enough to reduce aluminium oxide. Therefore, electrolysis is used.
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2Ag₂O → 4Ag + O₂ (on heating)
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Aluminium (most difficult), iron (moderate), gold (easiest).